邻苯二亚胺纤维素水溶液的荧光行为

目前，用于制造光致发光材料的基材均为合成高分子材料，如聚氯乙烯（ＰＶＣ）等热塑性材料以及不饱和聚酯等热固性材料［１］．天然高分子材料发光性能的研究并不多见．而与合成高分子相比，纤维素的结构特征决定了它易参与化学反应，可用以制备各种用途的功能材料，如高...     

PC／PBT共混体系的研究：Ⅰ.PC,PBT熔融共混时的酯交换反应

采用红外光谱、核磁共振等测试手段，系统地研究了ＰＣ、ＰＢＴ熔融共混时的酯交换反应，发现ＰＢＴ中残余的Ｔｉ催化剂会对酯交换反应起催化作用。通过加入能和Ｔｉ催化剂络合添加剂，可以控制酯交换程度，这为控制ＰＣ／ＰＢＴ合金的性能提供了一个非常有效的方法。     

Solar-Driven Artificial Carbon Cycle

Constituting the artificial carbon cycle,for example,through recycling CO₂ and converting CH₄ to value-added fuels and chemicals with solar energy,offers a sustainable future for humankind to tackle the global environmental issues and energy crisis.However,significant bottlenecks remain in such photocatalytic conversion,mainly related to the reaction activity and product selectivity.Herein,we share our efforts and systematic research progress on addressing the double bottlenecks for achieving solar-driven artificial carbon cycle,with specifically focusing on the photocatalytic CO₂ and CH₄ conversion.We further elucidate the common fundamentals behind various designed photocatalytic materials systems.Toward future development,we highlight the opportunities and challenges in the research field.     

Photodissociation of Cycloketones by Ultraintense Femtosecond Laser Pulses

ThestudyofphotoionizationandphotodissociationprocessesinducedbyintensefemtosecondlaserpuIses(>lo"W/cm')withpolyatomicmoleculesbecomesofinterestbecausesomenewphenomenahavebeenobserved'-3.Sofar,mostoftheinvestigationsfocusontheexperimentalexplorationofphotoionizationprocesses'-'.Butthephotoionizationmechanismofpolyatomicmoleculesinanintensefslaserfieldisstillambiguous'.,.Incontrasttothephotoionizationprocesses,theunderstandingoffragmentationofmolecularionisevenpoorer.Corkumetal,'.,'reportedthef…     

Synthesis,structure and DNA-binding studies on the 2-(3-chlorophenyl)imidazo[4,5-f]1,10-phenanthroline-bis(2,2′-bipy ridine)-ruthenium(II) complex

A new polypyridyl ligand, MCP {MCP = 2-(3-chlorophenyl)imidazo[4,5-f]1,10-phenanthroline} and its ruthenium(II) complex, [Ru(bpy)2(MCP)](ClO4)2· 0.5MeCN (bpy = 2,2-bipyridine), have been synthesized and characterized. The structure of the complex was determined by single crystal X-ray diffraction techniques. The MCP ligand is essentially planar and the stacking interactions between the ligands were observed in the crystal. [Ru(bpy)2(MCP)]2+ can strongly bind to Calf thymus DNA through intercalation of MCP ligand. The Cl substitute group has no significant effect on the spectral properties and DNA-binding behaviour of the complex.     

主动发起的融资融券交易对中国股票市场的影响

本文以融资买入和融券卖出为研究对象,分析了投资者主动发起的融资融券交易对股票回报、流动性和波动性的影响,给出了中国股票市场融资融券发展现状。研究发现,融资买入(融券卖出)对当日股票回报有显著为正(负)的影响,交易表现与政策制定动机——融资反映投资者看涨情绪、融券反映投资者看跌情绪一致。此外,融资买入(融券卖出)增加了(降低)股票流动性;融资买入(融券卖出)降低(增加)了股票波动性;融资融券对股票交易特征的影响有随时间逐渐改善的趋势。最后,本文发现融资融券对股票回报、流动性和波动性产生的影响与股票所在板块有关,随着中小板和创业板股票所占比重的增加,调整和优化融资融券对股票市场的影响仍然是监管者未来主要任务之一。     

The integrable hierarchy constructed from a pair of KdV-type hierarchies and its associatedW algebra

For any two arbitrary positive integers n and m, using them ^th KdV hierarchy and the (n+m)^th KdV hierarchy as building blocks, we are able to construct another integrable hierarchy (referred to as the (n, m)^th KdV hierarchy). TheW-algebra associated to the second Hamiltonian structure of the (n, m)^th KdV hierarchy (calledW(n, m) algebra) is isomorphic via a Miura map to the direct sum of aW _m -algebra, aW _n+m -algebra and an additionalU(1) current algebra. In turn, from the latter, we can always construct a representation of aW -algebra.     

Classification of (2,2)-stable unfoldings of map germs with codimensions ≤ 4

In this paper we classify (2,2)-stable unfoldings of map germs with codimensions 4 by means of the algorithm given in [4] by Wassermann.